Advances in Heterocyclic Chemistry, Vol. 58 by Alan R. Katritzky

Advances in Heterocyclic Chemistry, Vol. 58 by Alan R. Katritzky

By Alan R. Katritzky

The newest quantity within the Advances in Heterocyclic Chemistry sequence

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Amidyl radicals are generated with visible light irradiation in a controlled and efficient radical chain reaction (Scheme 30). 5913) and with H-atom donors ( Y - H) reduction of the amidyl radical occurs with formation of the indicative Y-S-2-pyridyl products. As is the case with N-chloroamides, amidyl radicals with suitable positioned alkenes generated from N-hydro- 38 JOHN L. ESKER AND MARTIN NEWCOME ISec. B H 87 SCHEME 29 xypyridine-2-thione imidate esters undergo efficient 5-exo cyclization.

48 11. Four-Membered Heterocycles. . ...... 54 s4 3 . Molecular Structure of 2-Phenylbenzotellurazole . . . . . 2. Reactions . . . . . . . . . . . . . . . . . . . . . . . . 3. Molecular Structure . . . . . . . . . . . . . . . . . . . . E. 1. . . . . . . . . . . . . . . . . . . F. 1,3-Thiatelluroles G. I ,2-Ditelluroles . 62 63 64 ............ .. A. 1-Hetera-2(3)(4)-telluracyclohexanes .

M. E. Kuehne and D. A. Horne. J . Org. Chem. 40, 1287 (1975). C. J . Michejda and D. H. Campbell, J . Am. Chem. Soc. 98,6728 (1976). C. J . Michejda and D. H. Campbell. , 577 (1977). P. Mackiewicz, R. Furstoss, B. Wagell, R. Cote. and J . Lessard. J . Org. Chem. 43, 3746 (1978). J . Lessard, R. Cote, P. Mackiewicz, R. Furstoss. and B. Wagell. J . Org. Chern. 43, 3750 (1978). C. J. Michejda. D. H. Campbell, D. H. Sieh, and S . R. Koepke, in “Organic Free Radicals” (W. A. ). Chapter 18. Am. Chem.

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