Alkaline-Earth Metal Compounds: Oddities and Applications by Ana Torvisco, Karin Ruhlandt-Senge (auth.), Sjoerd Harder

Alkaline-Earth Metal Compounds: Oddities and Applications by Ana Torvisco, Karin Ruhlandt-Senge (auth.), Sjoerd Harder

By Ana Torvisco, Karin Ruhlandt-Senge (auth.), Sjoerd Harder (eds.)

The sequence issues in Organometallic Chemistry offers serious overviews of study ends up in organometallic chemistry. As our realizing of organometallic constitution, houses and mechanisms raises, new methods are opened for the layout of organometallic compounds and reactions adapted to the desires of such assorted parts as natural synthesis, scientific learn, biology and fabrics technological know-how. therefore the scope of insurance incorporates a extensive diversity of issues in natural and utilized organometallic chemistry, the place new breakthroughs are being completed which are of importance to a bigger clinical viewers. the person volumes of themes in Organometallic Chemistry are thematic. evaluate articles are ordinarily invited through the amount editors.

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3 Properties of Post-Grignard Reagents . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1 NMR Studies . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2 Structural Characteristics . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4 Reactivity Investigations . . . . . . . . . . . . . . .

References . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . List of Abbreviations Ae Ar Bu 18-crown-6 Cp Diglyme Diox DME eÀ Et HMTETA L M Me Mes Naph Ph Pr R Solv THF THP Tipp TMEDA Tol TMTN Alkaline-earth metal Aryl Butyl 1,4,7,10,13,16,-Hexaoxacyclooctadecane Cyclopentadienyl Diethylene glycol dimethyl ether 1,4-Dioxane 1,2-Dimethoxyethane Electron Ethyl N,N,N0 ,N00 ,N000 ,N000 -Hexamethyltriethylenetetramine Ligand Metal Methyl 2,4,6-Trimetylphenyl Naphthyl Phenyl Propyl Substituent Solvent Tetrahydrofuran Tetrahydropyran 2,4,6-Tri-isopropylphenyl N,N,N0 ,N0 -Tetramethylethylenediamine 4-Methylphenyl N,N0 ,N00 -Trimethyl-1,4,7-triazacyclononane 31 34 35 38 42 44 47 47 50 57 58 59 61 65 Heavier Group 2 Grignard Reagents of the Type Aryl-Ae(L)n-X.

Ruhlandt-Senge Fig. 15 Crystal structure of [Ca(N(SiMe3)2)(18-crown6)][CPh3] (CPh3 or triphenylmethanide) [145]. Hydrogen atoms have been omitted for clarity. All non-carbon atoms are shown as shaded ellipsoids have been reported: reaction of heavy alkaline-earth alkoxide with benzyllithium [144] [Eq. (13)] and treatment of the alkaline-earth bis(bis(trimethylsilyl)amides with a lithium reagent [144–147] [Eq. (14)]. MðORÞ2 þ 2PhCH2 Li ! ðPhCH2 Þ2 M þ 2LiOR (13) where M ¼ Ba; R ¼ 2,4,6-tri-tertbutylphenyl.

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